There is no specific level requirement for any particular ore. Mining difficulty is random for every vein you encounter, but generally increases the deeper you go. As far as I know, silver ore is possible on level 2 and deeper.
In Amber client, you can always toggle shift+i and hover over cave walls with shift or ctrl+shift to see the name of the ore. So you can tell if it is silver without even mining it. Wiki is down right now, and "Ores" page there is very useful. But if you have "Hornblende", it is not silver.
